The latest developments in photochemistry on solid surfaces, i.e. photochemistry in heterogeneous systems, including liquid crystallines, are brought together for the first time in a single volume. Distinguished photochemists from various fields have contributed to the book which covers a number of important applications: molecular photo-devices for super-memory, photochemical vapor deposition to produce thin-layered electronic semiconducting materials, sensitive optical media, the control of photochemical reactions pathways, etc. Photochemistry on solid surfaces is now a major field and this book which provides an up-to-date and comprehensive overview of the subject will be of interest to a wide range of readers. Content: Edited by Page iii Copyright page Page iv Preface Pages xi-xii List of Contributors Pages xiii-xx Introduction Original Research Article Pages 1-4 Ikuzo Tanaka General Aspects of Photochemistry. Search for New Basic Types of Photochemical Reactions Original Research Article Pages 5-13 K. Tokumaru, T. Arai, T. Karatsu Fluorescence and Transient Absorption Spectra of Solid Surface: Development of Time-Resolved Total Internal Reflection Spectroscopy Original Research Article Pages 15-29 H. Masuhara Laser Flash Photolysis on Solid Surfaces Original Research Article Pages 30-47 F. Wilkinson, G.P. Kelly Excimer Formation with Pyrenes on Silica Surfaces Original Research Article Pages 48-78 K.A. Zachariasse Photophysics of Acridone, N-Methylacridone, Acridine, and Pyrene Adsorbed on Silica Gel Original Research Article Pages 79-92 S. Suzuki, T. Fujii Heterogeneous Molecular Environments Probed by Fluorophores Bonded to Chemically Modified Silica Gel— Fluorescence Decay Measurements Under a Microscope Original Research Article Pages 93-105 S. Hirayama, T. Kubo, H. Yamasaki Photoacoustic and Fluorescence Measurements of Energy Transfer in Adsorption Layers Original Research Article Pages 106-118 H.D. Breuer Photochemistry of Alkyl Ketones in the Adsorbed State: Effects of Solid Surfaces Upon the Photolysis Original Research Article Pages 119-137 M. Anpo Decomposition of Azocumene on Silica Surfaces Original Research Article Pages 138-148 J.E. Leffler, J.J. Zupancic Photolytic and Redox Mechanisms for the Photodecomposition of Ethanoic Acid Adsorbed Over Pure and Mixed Oxides Original Research Article Pages 149-167 M. Schiavello, V. Augugliaro, S. Coluccia, L. Palmisano, A. Sclafani ESR Studies of Alkyl Radicals Adsorbed on Porous Vycor Glass Original Research Article Pages 168-183 H.D. Gesser Chemiluminescence Properties of Adsorbed Biacridylidenes Original Research Article Pages 184-195 K. Maeda, S. Yamada Photochemistry of Dibenzyl Ketone Adsorbed on Size/Shape Selective Faujasite Zeolites. Steric Effects on Product Distributions Original Research Article Pages 197-215 N.J. Turro, Z. Zhang Photochemistry of Organic Cations at Charged Interfaces Original Research Article Pages 216-235 C.A. Backer, D.G. Whitten Electron Transfer Between Adsorbed Dye Molecules and Organic Crystals: Model Character of the Adsorption System for Certain Aspects in Photosynthesis Original Research Article Pages 236-253 K. Kemnitz, N. Nakashima, K. Yoshihara Inorganic Photochemical Reactions in Low Temperature Matrices and in the Surfaces of Solids Original Research Article Pages 255-271 T. Tominaga Photochemistry of Metal Carbonyls Physisorbed on Porous Vycor Glass Original Research Article Pages 272-287 H.D. Gafney Photochemistry of Silica-Adsorbed Fe(CO) 5 Original Research Article Pages 288-302 R.L. Jackson Photopreparation of Supported Metal Oxide and Metal Carbonyl Catalysts Original Research Article Pages 303-316 A. Morikawa, Y. Wada UV Laser Photodissociation of Small Molecules on Solid Surfaces Original Research Article Pages 317-328 H. Sato, M. Kawasaki Co 2 Laser Induced Surface Reaction Original Research Article Pages 329-338 M. Kawai Photochemical Aspects of Amorphous-Si Nucleation by Photo-CVD Original Research Article Pages 339-352 H. Hada, M. Kawasaki Photoprocesses on Fractal Surfaces Original Research Article Pages 353-374 A. Seri-Levy, J. Samuel, D. Farin, D. Avnir New Aspects in Area-Selective Electrode Reactions on Illuminated Semiconductors Original Research Article Pages 375-387 M. Okano, R. Baba, K. Itoh, A. Fujishima Photoluminescent Properties of Cadmium Sulfide Contacted with Gaseous Lewis Acids and Bases Original Research Article Pages 388-402 G.J. Meyer, E.R.M. Luebker, G.C. Lisensky, A.B. Ellis Fluorescence of Dye Molecules Adsorbed on Semiconductor Surfaces Original Research Article Pages 403-417 A.M. Ponte Goncalves Photostability of Near-Infrared Absorbing Organic Dyes in New Optical Media Original Research Article Pages 419-434 H. Nakazumi, T. Kitao Photoinduced Phase Transition in Liquid Crystals Original Research Article Pages 435-447 S. Tazuke, S. Kurihara Photochemical Surface Reactions of Polymeric Systems: Lithographic Applications Original Research Article Pages 448-468 H. Hiraoka Photoreactivity of Carbonyl Compounds in the Solid State Original Research Article Pages 469-480 Y. Ito Ketone Photochemistry as a Probe of Conformational Mobility in Nematic and Smectic Liquid Crystals Original Research Article Pages 481-500 W.J. Leigh Absolute Asymmetric Synthesis Via Photochemical Reactions of Chiral Crystals Original Research Article Pages 501-525 J.R. Scheffer, M. Garcia-Garibay Fluorescence Quenching of Pyrene as a Monitor of Intermolecular Diffusion and Intramolecular Chain Bending in Cholesteric Liquid Crystalline Phases (1) Original Research Article Pages 526-550 M.F. Sonnenschein, R.G. Weiss Dynamics of Excited State Relaxations in Some Proteins Original Research Article Pages 551-565 F. Tanaka, N. Mataga Subject Index Pages 567-581